Emerging Guidelines for the Design of Organic Semiconductors

Speaker: Prof. Guillermo C. Bazan (University of California, Santa Barbara)

Title: Emerging Guidelines for the Design of Organic Semiconductors

Time: 10:00 AM, Feb. 2nd (Friday)

Location: 909-B, Dushu Lake Campus

 

Abstract:

This presentation will initially focus on the impact of molecular structure on the organizational and functional properties of organic semiconductors. Special emphasis will be placed on understanding organizational principles under kinetically confined conditions as a result of non-covalent interactions; for instance, the diversity of conformational isomers, presence of solvent additives, and molecular reorganizations that may favor amorphous or crystalline phases. Examples will be provided that illustrate translation of morphological control into more efficient optoelectronic devices, including organic solar cells. 

The second part of the seminar will center on the properties of narrow bandgap conjugated polyelectrolytes, and in particular how the electrostatic field of the adjacent charged groups can be used to modulate doping preferences of the electronically delocalized backbone. New emerging applications for these materials will be demonstrated, including the ability to dope other semiconductors, including carbon nanotubes and graphene, and to serve as relays for electron transport from living anaerobic microorganisms.

 

Speaker Biography:

EDUCATION      

California Institute of Technology, Postdoctoral Fellow, November 1990- May 1992

Massachusetts Institute of Technology, Ph.D. awarded in Inorganic Chemistry, February 1991

University of Ottawa, B. Sc. (Honors) awarded in Chemistry (Summa Cum Laude),

PROFESSIONAL EXPERIENCE

1999-        Professor, Department of Materials, UCSB

1998-        Professor, Department of Chemistry & Biochemistry, UCSB

1997-98    Associate Professor, Department of Chemistry, University of Rochester

1992-97    Assistant Professor, Department of Chemistry, University of Rochester

AWARDS and RECOGNITIONS

Frontiers in Chemistry Named Lecture, Case Western Reserve University; Thomson Reuter “Most Influential Scientific Minds”, 2015; Fellow of the Royal Society of Chemistry, 2014; Top 50 Material Scientists by Citation and Impact, Thompson Reuters, 2011; Macromolecules Advisory Board, 2009; Professor of the Chang Jiang Scholars Professor, 2009; Advanced Materials Editorial Advisory Board, 2008; Fellow of the AAAS, 2007; American Chemical Society Cope Scholar Award, 2006; Bessel Award, Humboldt Foundation, 2005; NSF Special Creativity Award, 2003; Union Carbide Innovation Award, 1999 and 1998; Closs Lecturer, University of Chicago, 1997; Camille and Henry Dreyfus Teacher-Scholar Award, 1996-1998; Sloan Research Fellow Award, 1996-1998; NSF CAREER Award, 1995-1998; Dreyfus New Faculty Award, 1992-1993; NSERCC Postdoctoral Fellowship, November 1990-May 1992; NSERCC 1967 Science and Engineering Scholarship, September 1986-June 1990.

RELEVANT PUBLICATIONS

Out of a total of 545 peer-reviewed journal articles and 35 awarded or pending patents

(1) Efficiency Enhancement in Low-Bandgap Polymer Solar Cells by Processing with Alkane Dithiols, Peet, J.; Kim, J. Y.; Coates, N. E.; Ma, W. L.; Moses, D.; Heeger, A. J.; Bazan, G. C., Nat. Mater.20077, 497-500.

(2) Design and Synthesis of Molecular Donors for Solution-Processed High-Efficiency Organic Solar Cells, Coughlin, J. E.; Henson, Z. B.; Welch, G. C.; Bazan, G. C., Acc. Chem. Res., 201447, 257-270.

(3) DNA Detection using Water-Soluble Conjugated Polymers and Peptide Nucleic Acid Probes, Gaylord, B. S.; Heeger, A. J.; Bazan, G. C., Proc. Nat. Acad. Sci., 200299, 10954-10957.

(4) Electrochemical Considerations for Determining Absolute Frontier Orbital Energy Levels of Conjugated Polymers for Solar Cell Applications, Cardona, C. M; Li, W.; Kaifer, A. E.;  Stockdale, D.;  Bazan, G. C.,  Adv. Mater.201123, 2367-2371.

(5) Ferrocene-Based Conjugated Oligoelectrolyte Catalyzes Bacterial Electrode Respiration, Kirchhofer, N.D.; Rengert, Z.D.; Dahlquist, F.W.; Nguyen, T.-Q.; Bazan, G.C., Chem.22017, 164-167.